But does the striker not know it's international week?
Judging by his message on his Instagram account today and the fact that he is not in Italy's current squad for their matches against Netherlands and Norway, possibly not...
He wrote alongside a caption of him in Liverpool gear: "Looking forward to my first game in ANFIELD".
He'll have to wait another 10 days before he is unleashed at the Reds' famous home - when Liverpool take on the unbeaten Aston Villa in next Saturday's evening kick-off.
But Anfield has been far from a happy hunting ground for Balotelli in the past.
Mario Balotelli: The funniest stories
Mario Balotelli: The funniest stories
When a youngster asked for an autograph outside Manchester City's training ground, Balotelli demanded to know why the boy was playing truant. After the child revealed he was being bullied, Balotelli drove the boy and his mother to the school in question so he could tackle the bully himself. He demanded to see the headmaster to make him aware of the issue and then mediated between the two boys to resolve the problem. A source said: 'Mario feels strongly about bullying.' Read the full story here.
After gambling at Manchester's 235 Casino, Balotelli walked away with winnings of £25,000. Feeling generous, he gave a homeless man 'with ginger dreadlocks and a beard' £1,000. Click here for the full story.
3/17 Parking fines
During his time in Manchester, Balotelli racked up £10,000 in parking fines and had his white Maserati impounded 27 times. Once he was pulled over by the police who wanted to enquire why he had £5,000 in cash on his front seat. Balotelli reorted: 'Because I am rich.' Click here for the full story.
Balotelli was 'bored', so threw darts at Manchester City youth team players to pass the time. Click here for the full story.
Balotelli explained prior to Euro 2012 how he would deal with racists: 'I will not accept racism at all. It's unacceptable. If someone throws a banana at me in the street, I will go to jail, because I will kill them.'
In a pre-season friendly for AC Milan, two fans ran onto the pitch to demand a selfie with the striker. Rather than shy away like most would in such a situation, Balotelli was more than happy to oblige.
Mario isn't a one trick pony. He can also iron, dance and read - all at the same time. Click here to watch.
For reasons never fully explained, Balotelli once sported a chicken hat. Thankfully it was a trend that never caught on.
Getty Images; Sky News
A bright spark at the body that co-ordinates firework safety material enlisted Balotelli soon after it was reported that some had been set off in the bathroom of his Manchester mansion.
10/17 Why always me?
The day those stories emerged, Balotelli scored for City in the Manchester derby, giving him the perfect opportunity to reveal *that* t-shirt.
11/17 The Queen
The Queen may be wary of Balotelli's return to England. During the World Cup, he said he wanted a kiss from Her Royal Highness should Italy do England a favour by beating Costa Rica. Thankfully for everyone involved, they didn't.
During a Europa League defeat to Dynamo Kiev, Balotelli had to be substituted in the 57th minute with his face swelling up. It emerged afterwards that the Italian is allergic to some types of grass.
During an Inter Milan press conference to announce the appointment of Andrea Stramaccioni as interim-manager, Balotelli interrupted proceedings to say hello. He was enjoying a day-off from Manchester City at the time. Click here to watch.
Balotelli's naked torso was to be one of the defining images of Euro 2012 - but he's not overly keen on celebrating goals. 'I don't celebrate goals, I'm just doing my job,' he infamously said. 'Does a postman celebrate when he delivered the mail?'
Balotelli has always appeared to be well loved by his team-mates. Perhaps it's the pranks he plays, like this one on Edin Dzeko. Click here to watch.
Balotelli was reportedly questioned by police in Italy when he was found taking a look around the grounds of a women's prison in Brescia. Apparently he simply fancied having a look. Click here for the full story.
Balotelli's relationship with former Manchester City boss Roberto Mancini was a complicated one. It has been described as a father-and-son type relationship - only the sort where they fight each other during training.
EAMONN & JAMES CLARKE
In his first match at the ground, Manchester City's 3-0 defeat in April 2011, he was so poor he substituted despite having earlier come on as substitute himself.
Then in his next Anfield appearance, his was sent off in the 83rd minutes after picking up two yellow cards in a 1-1 draw in November 2011
And in his last game at Anfield for City, in a 2-2 draw in August 2012, he lasted 62 minutes before being replaced by Edin Dzeko.
Balotelli had said when he joined that the opposing Liverpool fans "weren't nice with him" when he played against them.
"Whenever I played against Liverpool, the fans weren't nice with me but that's normal - it's football!" he said.
"Now that I play for Liverpool, I can see the expectation in people. They're very happy and that makes me very happy at the same time."
By the looks of this Facebook video that Balotelli uploaded today, their relationship is well and truly back on.
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