The Hollywood Foreign Press Association, which conducts the awards ceremony, made the announcement on Wednesday.
"The HFPA is proud to announce that Sam Rockwell and @jes_chastain will be presenters at the 76th Golden Globe Awards!" reads a message posted from the Golden Globes' Twitter account.
It is not known yet which award the acting duo, who both starred in Woman Walks Ahead in 2017, will announce.
The Golden Globes traditionally have a star-studded list of presenters, with some of the year's highest profile names handing out the many awards.
Rockwell earned a Golden Globe nomination this year for his role as George W Bush in Vice. He won the Golden Globe for Best Supporting Actor in a Motion Picture last year for his role in Three Billboard Outside Ebbing, Missouri.
Chastain won the Golden Globe for Best Actress in a Motion Picture – Drama in 2013 for her performance in Zero Dark Thirty.
The Golden Globes will be hosted by Sandra Oh and Andy Samberg this year.
The ceremony will take place on 6 January at the Beverly Hilton hotel in Beverly Hills, California. It will air on NBC from 5 to 8pm PT and from 8 to 11 pm ET.
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