The Catalan outfit are the reigning champions of Spain’s domestic cup competition, but the side they defeated in last season’s final, Athletic Club, had their revenge thanks to a 3-2 victory in extra time.
It had initially seemed as though the Basque side would progress in 90 minutes after a wild start and end to the match.
Iker Muniain netted just two minutes in, before Ferran’s equaliser midway through the first half - a fine curled effort into the far corner. Inigo Martinez scrambled home from close range just four minutes from full-time, after Gerard Pique inexplicably let the ball run across himself almost on the goal line, but Pedri came to Barcelona’s rescue with a fierce strike in stoppage-time after Dani Alves’ acrobatic assist.
That forced extra time, where Muniain again stepped up to score a penalty - given after a VAR review for a handball against Jordi Alba - and this time there was no way back for Xavi Hernandez’s side.
Earlier in the evening, Real Madrid were also taken to extra time and had to come from behind to beat Elche, with both teams seeing players sent-off.
Marcelo was dismissed for Los Blancos toward the end of the first period following a 90-minute stalemate, after a last-man foul. From the subsequent free-kick, initially blocked back out, Gonzalo Verdu fired Elche via a deflection off Dani Ceballos.
Another deflection levelled matters just after the restart, Ceballos’ shot bouncing in off Isco, before Eden Hazard scored his first goal of the season in any competition, rounding the onrushing ‘keeper to clip home with five minutes left.
There was still time for a contentious ending as Fidel rattled in a would-be equaliser, only to see it chalked off for an apparent foul by a team-mate in the build-up. All that came after former Southampton forward Guido Carrillo somehow contrived to hit the crossbar from just one yard out for Elche, mere minutes into the game.
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